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1.
Chemical Product and Company Identification |
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Synonyms:
Formaldehyde 37%; Formalin; Morbicid Acid; Methylene
Oxide; Methyl aldehyde
CAS No.: 50-00-0
Molecular Weight: 30.03
Chemical Formula: HCHO and CH3OH in water |
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Company Information:
ChemicalStore.com
A Division of New Jersey Industrial Research
1059 Main Avenue
Clifton, NJ 07011 For Information, call:
(973) 405-6248 |
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2. Hazards
Identification |
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Emergency Overview
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POISON! DANGER! SUSPECT CANCER HAZARD. MAY CAUSE CANCER. Risk
of cancer depends on level and duration of exposure. VAPOR
HARMFUL. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. STRONG
SENSITIZER. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. CANNOT
BE MADE NONPOISONOUS. FLAMMABLE LIQUID AND VAPOR. |
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Health Rating: 3 - Severe (Poison)
Flammability Rating: 2 - Moderate
Reactivity Rating: 2 - Moderate
Contact Rating: 3 - Severe (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT
HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
Storage Color Code: Red (Flammable) |
0 - Minimum Hazard
1 - Slight Hazard
2 - Moderate Hazard
3 - Serious Hazard
4 - Severe Hazard |

H = Health
F = Fire
R = Reactivity |
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Potential Health Effects
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Inhalation:
May cause sore throat, coughing, and shortness of breath. Causes
irritation and sensitization of the respiratory tract.
Concentrations of 25 to 30 ppm cause severe respiratory tract
injury leading to pulmonary edema and pneumonitis. May be fatal
in high concentrations.
Ingestion:
Can cause severe abdominal pain, violent vomiting, headache, and
diarrhea. Larger doses may produce decreased body temperature,
pain in the digestive tract, shallow respiration, weak irregular
pulse, unconsciousness and death. Methanol component affects the
optic nerve and may cause blindness.
Skin Contact:
Toxic. May cause irritation to skin with redness, pain, and
possibly burns. Skin absorption may occur with symptoms
paralleling those from ingestion. Formaldehyde is a severe skin
irritant and sensitizer. Contact causes white discoloration,
smarting, cracking and scaling.
Eye Contact:
Vapors cause irritation to the eyes with redness, pain, and
blurred vision. Higher concentrations or splashes may cause
irreversible eye damage.
Chronic Exposure:
Frequent or prolonged exposure to formaldehyde may cause
hypersensitivity leading to contact dermatitis. Repeated or
prolonged skin contact with formaldehyde may cause an allergic
reaction in some people. Vision impairment and enlargement of
liver may occur from methanol component. Formaldehyde is a
suspected carcinogen (positive animal inhalation studies).
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems, or
impaired liver, kidney or respiratory function may be more
susceptible to the effects of the substance. Previously exposed
persons may have an allergic reaction to future exposures. |
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3.
First Aid Measures |
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Inhalation:
Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Call a
physician.
Ingestion:
If swallowed and the victim is conscious, dilute, inactivate, or
absorb the ingested formaldehyde by giving milk, activated
charcoal, or water. Any organic material will inactivate
formaldehyde. Keep affected person warm and at rest. Get medical
attention immediately. If vomiting occurs, keep head lower than
hips.
Skin Contact:
In case of contact, immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing and
shoes. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention immediately.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15
minutes, lifting lower and upper eyelids occasionally. Get
medical attention immediately. |
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4.
Fire Fighting Measures |
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Fire:
Flash point: 60C (140F) CC
Autoignition temperature: 300C (572F)
Flammable limits in air % by volume:
lel: 7.0; uel: 73
Flammable liquid and vapor! Gas vaporizes readily from solution
and is flammable in air.
Explosion:
Above flash point, vapor-air mixtures are explosive within
flammable limits noted above. Containers may explode when
involved in a fire.
Fire Extinguishing Media:
Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved
self-contained breathing apparatus with full facepiece operated
in the pressure demand or other positive pressure mode. Water
may be used to flush spills away from exposures and to dilute
spills to non-flammable mixtures. |
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5.
Disposal Considerations |
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Whatever cannot be saved for recovery or recycling should be
handled as hazardous waste and sent to a RCRA approved
incinerator or disposed in a RCRA approved waste facility.
Processing, use or contamination of this product may change the
waste management options. State and local disposal regulations
may differ from federal disposal regulations. Dispose of
container and unused contents in accordance with federal, state
and local requirements. |
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DISCLAIMER: New Jersey Industrial Research Center provides the
information contained herein in good faith but makes no
representation as to its comprehensiveness or accuracy. This
document is intended only as a guide to the appropriate
precautionary handling of the material by a properly trained
person using this product. Individuals receiving the
information must exercise their independent judgment in
determining its appropriateness for a particular purpose. New
Jersey Industrial Research Center is not responsible for damages
resulting from use of or reliance upon this information. |